Phase Diagram For Carbon Dioxide

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Decoding the Mysteries: A Comprehensive Guide to the Phase Diagram for Carbon Dioxide



Introduction:

Have you ever wondered why dry ice sublimates – transforming directly from a solid to a gas? Or how carbon dioxide can exist as a liquid under specific conditions? The answer lies within its fascinating phase diagram. This comprehensive guide delves into the intricacies of the carbon dioxide phase diagram, explaining its features, interpretations, and real-world applications. We'll break down complex concepts into easily digestible information, ensuring you gain a firm understanding of this crucial tool for understanding the behavior of this ubiquitous compound. Prepare to unlock the secrets hidden within the curves and regions of the carbon dioxide phase diagram!


1. Understanding Phase Diagrams: A Quick Overview

Before diving into the specifics of carbon dioxide, let's establish a foundational understanding of phase diagrams. A phase diagram is a graphical representation showing the conditions (temperature and pressure) at which different phases of a substance – solid, liquid, and gas – exist in equilibrium. The lines on the diagram represent the boundaries between these phases, indicating the specific temperature and pressure combinations where transitions occur (melting, freezing, boiling, condensation, sublimation, and deposition). Understanding these lines is key to interpreting the behavior of any substance, including carbon dioxide.


2. The Unique Features of the Carbon Dioxide Phase Diagram

The carbon dioxide phase diagram is notably different from that of water. Its most striking feature is the critical point. This point represents the temperature and pressure above which the distinction between liquid and gas phases disappears. Beyond the critical point, carbon dioxide exists as a supercritical fluid – a state possessing properties of both liquids and gases. Another key feature is the triple point, where all three phases (solid, liquid, and gas) coexist in equilibrium. Unlike water, the triple point of carbon dioxide is at a pressure significantly above atmospheric pressure. This explains why we don't see liquid CO2 at standard atmospheric conditions. Finally, note the substantial slope of the solid-liquid equilibrium line. This indicates that increasing pressure on solid CO2 actually lowers its melting point – a unique characteristic of this substance.


3. Interpreting the Regions of the Carbon Dioxide Phase Diagram

The phase diagram is divided into distinct regions:

Solid Region: This region represents the conditions where carbon dioxide exists as dry ice (solid CO2).

Liquid Region: This region depicts conditions where carbon dioxide exists as a liquid. Note that this region is only accessible at pressures significantly above atmospheric pressure.

Gas Region: This region represents the conditions under which carbon dioxide exists as a gas. This is the most common state of CO2 under standard atmospheric conditions.

Supercritical Fluid Region: This region lies above the critical point and represents the supercritical fluid state. In this state, CO2 possesses unique solvent properties, making it valuable in various industrial applications.


4. Real-World Applications Based on the Phase Diagram

The understanding and application of the CO2 phase diagram are crucial in numerous industries:

Carbonated Beverages: The pressurization process used to dissolve CO2 in beverages directly relates to the liquid-gas equilibrium line on the phase diagram.

Dry Ice Production: The sublimation of solid CO2 (dry ice) is directly explained by the phase diagram, revealing the conditions under which this process occurs efficiently.

Supercritical Fluid Extraction: The unique solvent properties of supercritical CO2 are exploited in various extraction processes, such as decaffeination and the extraction of essential oils. The phase diagram guides the selection of appropriate temperature and pressure conditions for optimal extraction.

Fire Suppression Systems: Liquid CO2 is used in some fire suppression systems. The phase diagram helps determine the optimal conditions for storage and release of the liquid to effectively extinguish fires.


5. Beyond the Basics: Advanced Concepts

The CO2 phase diagram can be further analyzed to understand phenomena like:

Metastable States: Under certain conditions, CO2 can exist in metastable states, meaning it's not in its most thermodynamically stable form. For instance, supercooled liquid CO2 can exist below its freezing point under specific circumstances.

Isobars and Isotherms: The phase diagram can also be analyzed by plotting isobars (lines of constant pressure) and isotherms (lines of constant temperature) to gain a deeper understanding of the phase transitions.


Article Outline: Decoding the Mysteries: A Comprehensive Guide to the Phase Diagram for Carbon Dioxide

I. Introduction
Hook and overview of the article's content.
Importance of understanding the CO2 phase diagram.

II. Understanding Phase Diagrams
Definition and basic principles of phase diagrams.
Explanation of key components: temperature, pressure, phase boundaries.

III. The Unique Features of the Carbon Dioxide Phase Diagram
Discussion of the critical point and its significance.
Explanation of the triple point and its implications.
Analysis of the solid-liquid equilibrium line and its unusual slope.

IV. Interpreting the Regions of the Carbon Dioxide Phase Diagram
Detailed explanation of the solid, liquid, gas, and supercritical fluid regions.
Visual aids (diagram) to aid understanding.

V. Real-World Applications Based on the Phase Diagram
Examples from various industries: beverages, dry ice production, supercritical fluid extraction, fire suppression.
Practical implications of the CO2 phase diagram.

VI. Beyond the Basics: Advanced Concepts
Discussion of metastable states and their relevance.
Explanation of isobars and isotherms and their use in analysis.

VII. Conclusion
Summary of key takeaways.
Emphasis on the importance of the CO2 phase diagram in scientific and industrial contexts.


Frequently Asked Questions (FAQs)

1. What is the critical point of carbon dioxide? The critical point of CO2 is approximately 31.1 °C and 73.8 bar.

2. Why doesn't CO2 exist as a liquid at standard atmospheric pressure? Because the triple point of CO2 is above atmospheric pressure. At atmospheric pressure, solid CO2 sublimates directly to gas.

3. What is a supercritical fluid? A supercritical fluid is a state of matter beyond the critical point, possessing properties of both liquids and gases.

4. How is the CO2 phase diagram used in the beverage industry? It helps determine the pressure needed to dissolve CO2 in beverages.

5. What are the applications of supercritical CO2 extraction? It's used in decaffeination, extraction of essential oils, and other processes.

6. What is the triple point of carbon dioxide? The triple point of CO2 is approximately -56.6 °C and 5.185 bar.

7. How does pressure affect the melting point of CO2? Increasing pressure lowers the melting point of CO2.

8. What is the significance of the solid-liquid equilibrium line? It indicates the conditions under which solid and liquid CO2 coexist in equilibrium.

9. What are metastable states in the context of the CO2 phase diagram? These are states where CO2 is not in its most thermodynamically stable phase, such as supercooled liquid CO2.



Related Articles:

1. Supercritical Fluid Extraction: Principles and Applications: A detailed exploration of supercritical fluid extraction techniques using CO2.

2. The Thermodynamics of Phase Transitions: A deeper dive into the theoretical aspects of phase transitions and their relationship to phase diagrams.

3. Dry Ice Safety and Handling Procedures: A practical guide on safely handling and using dry ice.

4. Carbon Dioxide in the Atmosphere and Climate Change: Discussion of CO2's role in the Earth's climate system.

5. Phase Diagrams of Other Substances: A Comparison: A comparative analysis of the phase diagrams of various substances, highlighting similarities and differences.

6. Industrial Applications of Carbon Dioxide: A broader look at various industrial uses of CO2.

7. The Properties of Supercritical Carbon Dioxide: A detailed examination of the unique properties of supercritical CO2.

8. Designing and Optimizing Supercritical CO2 Extraction Processes: A guide for engineers and scientists on optimizing supercritical CO2 extraction.

9. The Role of Pressure and Temperature in Chemical Reactions: Explores the impact of pressure and temperature on chemical reactions, including those involving CO2.


  phase diagram for carbon dioxide: Chemistry Bruce Averill, Patricia Eldredge, 2007 Emphasises on contemporary applications and an intuitive problem-solving approach that helps students discover the exciting potential of chemical science. This book incorporates fresh applications from the three major areas of modern research: materials, environmental chemistry, and biological science.
  phase diagram for carbon dioxide: General Chemistry Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette, 2010-05
  phase diagram for carbon dioxide: Carbon in Earth's Interior Craig E. Manning, Jung-Fu Lin, Wendy L. Mao, 2020-04-03 Carbon in Earth's fluid envelopes - the atmosphere, biosphere, and hydrosphere, plays a fundamental role in our planet's climate system and a central role in biology, the environment, and the economy of earth system. The source and original quantity of carbon in our planet is uncertain, as are the identities and relative importance of early chemical processes associated with planetary differentiation. Numerous lines of evidence point to the early and continuing exchange of substantial carbon between Earth's surface and its interior, including diamonds, carbon-rich mantle-derived magmas, carbonate rocks in subduction zones and springs carrying deeply sourced carbon-bearing gases. Thus, there is little doubt that a substantial amount of carbon resides in our planet's interior. Yet, while we know it must be present, carbon's forms, transformations and movements at conditions relevant to the interiors of Earth and other planets remain uncertain and untapped. Volume highlights include: - Reviews key, general topics, such as carbonate minerals, the deep carbon cycle, and carbon in magmas or fluids - Describes new results at the frontiers of the field with presenting results on carbon in minerals, melts, and fluids at extreme conditions of planetary interiors - Brings together emerging insights into carbon's forms, transformations and movements through study of the dynamics, structure, stability and reactivity of carbon-based natural materials - Reviews emerging new insights into the properties of allied substances that carry carbon, into the rates of chemical and physical transformations, and into the complex interactions between moving fluids, magmas, and rocks to the interiors of Earth and other planets - Spans the various chemical redox states of carbon, from reduced hydrocarbons to zero-valent diamond and graphite to oxidized CO2 and carbonates - Captures and synthesizes the exciting results of recent, focused efforts in an emerging scientific discipline - Reports advances over the last decade that have led to a major leap forward in our understanding of carbon science - Compiles the range of methods that can be tapped tap from the deep carbon community, which includes experimentalists, first principles theorists, thermodynamic modelers and geodynamicists - Represents a reference point for future deep carbon science research Carbon in Planetary Interiors will be a valuable resource for researchers and students who study the Earth's interior. The topics of this volume are interdisciplinary, and therefore will be useful to professionals from a wide variety of fields in the Earth Sciences, such as mineral physics, petrology, geochemistry, experimentalists, first principles theorists, thermodynamics, material science, chemistry, geophysics and geodynamics.
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  phase diagram for carbon dioxide: Equations of State for Fluids and Fluid Mixtures J.V. Sengers, R.F. Kayser, C.J. Peters, H.J. White, 2000-10-30 This book has been prepared under the auspices of Commission I.2 on Thermodynamics of the International Union of Pure and Applied Chemistry (IUPAC). The authors of the 18 chapters are all recognized experts in the field. The book gives an up-to-date presentation of equations of state for fluids and fluid mixtures. All principal approaches for developing equations of state are covered. The theoretical basis and practical use of each type of equation is discussed and the strength and weaknesses of each is addressed. Topics addressed include the virial equation of state, cubic equations and generalized van der Waals equations, perturbation theory, integral equations, corresponding stated and mixing rules. Special attention is also devoted to associating fluids, polydisperse fluids, polymer systems, self-assembled systems, ionic fluids and fluids near critical points.
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  phase diagram for carbon dioxide: Introduction to Planetary Science Gunter Faure, Teresa M. Mensing, 2007-05-04 This textbook details basic principles of planetary science that help to unify the study of the solar system. It is organized in a hierarchical manner so that every chapter builds upon preceding ones. Starting with historical perspectives on space exploration and the development of the scientific method, the book leads the reader through the solar system. Coverage explains that the origin and subsequent evolution of planets and their satellites can be explained by applications of certain basic principles of physics, chemistry, and celestial mechanics and that surface features of the solid bodies can be interpreted by principles of geology.
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  phase diagram for carbon dioxide: High-Pressure Fluid Phase Equilibria Ulrich K Deiters, Thomas Kraska, 2012-04-26 The book begins with an overview of the phase diagrams of fluid mixtures (fluid = liquid, gas, or supercritical state), which can show an astonishing variety when elevated pressures are taken into account; phenomena like retrograde condensation (single and double) and azeotropy (normal and double) are discussed. It then gives an introduction into the relevant thermodynamic equations for fluid mixtures, including some that are rarely found in modern textbooks, and shows how they can they be used to compute phase diagrams and related properties. This chapter gives a consistent and axiomatic approach to fluid thermodynamics; it avoids using activity coefficients. Further chapters are dedicated to solid-fluid phase equilibria and global phase diagrams (systematic search for phase diagram classes). The appendix contains numerical algorithms needed for the computations. The book thus enables the reader to create or improve computer programs for the calculation of fluid phase diagrams. - introduces phase diagram classes, how to recognize them and identify their characteristic features - presents rational nomenclature of binary fluid phase diagrams - includes problems and solutions for self-testing, exercises or seminars
  phase diagram for carbon dioxide: Atkins' Physical Chemistry Peter Atkins, Julio de Paula, 2010 This volume features a greater emphasis on the molecular view of physical chemistry and a move away from classical thermodynamics. It offers greater explanation and support in mathematics which remains an intrinsic part of physical chemistry.
  phase diagram for carbon dioxide: Natural Gas Hydrates John Carroll, 2009-07-10 The petroleum industry spends millions of dollars every year to combat the formation of hydrates-the solid, crystalline compounds that form from water and small molecules-that cause problems by plugging transmission lines and damaging equipment. They are a problem in the production, transmission and processing of natural gas, and it is even possible for them to form in the reservoir itself if the conditions are favorable. Natural Gas Hydrates is written for the field engineer working in the natural gas industry. This book explains how, when and where hydrates form, while providing the knowledge necessary to apply remedies in practical applications. New to the second edition, the use of new inhibitors: Kinetic Inhibitors and Anticoagulants and the topic of kinetics of hydrates. How fast do they form? How fast do they melt? New chapters on Hydrates in Nature, hydrates on the seafloor and a new section has also been added regarding the misconceptions about water dew points. Chapters on Hydrate Types and Formers, Computer Methods, Inhibiting Hydrate Formation with Chemicals, Dehydration of Natural Gas and Phase Diagrams Hydrate Dehydration of Natural Gas and Phase Diagrams have been expanded and updated along with the companion website. - Understand what gas hydrates are, how they form and what can be done to combat their formation - Avoid the same problems BP experienced with clogged pipelines - Presents the four most common approaches to evaluate hydrates: heat, depressurization, inhibitor chemicals, and dehydration
  phase diagram for carbon dioxide: A-level Chemistry E. N. Ramsden, 2000 Each topic is treated from the beginning, without assuming prior knowledge. Each chapter starts with an opening section covering an application. These help students to understand the relevance of the topic: they are motivational and they make the text more accessible to the majority of students. Concept Maps have been added, which together with Summaries throughout, aid understanding of main ideas and connections between topics. Margin points highlight key points, making the text more accessible for learning and revision. Checkpoints in each chapter test students' understanding and support their private study.
  phase diagram for carbon dioxide: Supercritical Carbon Dioxide Maartje F. Kemmere, Thierry Meyer, 2006-05-12 Recently, supercritical fluids have emerged as more sustainable alternatives for the organic solvents often used in polymer processes. This is the first book emphasizing the potential of supercritical carbon dioxide for polymer processes from an engineering point of view. It develops a state-of-the-art overview on polymer fundamentals, polymerization reactions and polymer processing in supercritical carbon dioxide. The book covers topics in a multidisciplinary approach starting from polymer chemistry and thermodynamics, going through monitoring, polymerization processes and ending with polymer shaping and post-processing. The authors are internationally recognized experts from different fields in polymer reaction engineering in supercritical fluids. The book was initiated by the Working Party on Polymer Reaction Engineering of the European Federation of Chemical Engineering and further renowned international experts.
  phase diagram for carbon dioxide: Chemistry3 Andrew Burrows, John Holman, Simon Lancaster, Andrew Parsons, Tina Overton, Gwen Pilling, Gareth Price, 2021 Chemistry is widely considered to be the central science: it encompasses concepts on which all other branches of science are developed. Yet, for many students entering university, gaining a firm grounding in chemistry is a real challenge. Chemistry3 responds to this challenge, providingstudents with a full understanding of the fundamental principles of chemistry on which to build later studies.Uniquely amongst the introductory chemistry texts currently available, Chemistry3's author team brings together experts in each of organic, inorganic, and physical chemistry with specialists in chemistry education to provide balanced coverage of the fundamentals of chemistry in a way that studentsboth enjoy and understand.The result is a text that builds on what students know already from school and tackles their misunderstandings and misconceptions, thereby providing a seamless transition from school to undergraduate study. Written with unrivalled clarity, students are encouraged to engage with the text andappreciate the central role that chemistry plays in our lives through the unique use of real-world context and photographs.Chemistry3 tackles head-on two issues pervading chemistry education: students' mathematical skills, and their ability to see the subject as a single, unified discipline. Instead of avoiding the maths, Chemistry3 provides structured support, in the form of careful explanations, reminders of keymathematical concepts, step-by-step calculations in worked examples, and a Maths Toolkit, to help students get to grips with the essential mathematical element of chemistry. Frequent cross-references highlight the connections between each strand of chemistry and explain the relationship between thetopics, so students can develop an understanding of the subject as a whole.Digital formats and resourcesChemistry3 is available for students and institutions to purchase in a variety of formats, and is supported by online resources.The e-book offers a mobile experience and convenient access along with functionality tools, navigation features, and links that offer extra learning support: www.oxfordtextbooks.co.uk/ebooksThe e-book also features interactive animations of molecular structures, screencasts in which authors talk step-by-step through selected examples and key reaction mechanisms, and self-assessment activities for each chapter. The accompanying online resources will also include, for students:DT Chapter 1 as an open-access PDF;DT Chapter summaries and key equations to download, to support revision;DT Worked solutions to the questions in the book.The following online resources are also provided for lecturers:DT Test bank of ready-made assessments for each chapter with which to test your studentsDT Problem-solving workshop activities for each chapter for you to use in classDT Case-studies showing how instructors are successfully using Chemistry3 in digital learning environments and to support innovative teaching practicesDT Figures and tables from the book
  phase diagram for carbon dioxide: NASA Technical Note United States. National Aeronautics and Space Administration, 1960
  phase diagram for carbon dioxide: Chemistry 2e Paul Flowers, Richard Langely, William R. Robinson, Klaus Hellmut Theopold, 2019-02-14 Chemistry 2e is designed to meet the scope and sequence requirements of the two-semester general chemistry course. The textbook provides an important opportunity for students to learn the core concepts of chemistry and understand how those concepts apply to their lives and the world around them. The book also includes a number of innovative features, including interactive exercises and real-world applications, designed to enhance student learning. The second edition has been revised to incorporate clearer, more current, and more dynamic explanations, while maintaining the same organization as the first edition. Substantial improvements have been made in the figures, illustrations, and example exercises that support the text narrative. Changes made in Chemistry 2e are described in the preface to help instructors transition to the second edition.
  phase diagram for carbon dioxide: The Atmospheric Environment Michael B. McElroy, 2002-05-05 This introduction to the physics and chemistry of Earth's atmosphere with an account of relevant aspects of ocean science, treats atmospheric science and the climate as an integrated whole, and makes explicit the policy implications of what is known. Its critical account of steps taken by the international community to address the issue of climatic change highlights the challenge of dealing with a global issue for which the political and economic stakes are high, where uncertainties are common and where there is a need for clear thinking and informed policy.
  phase diagram for carbon dioxide: Chemical Engineering Principles and Applications Nuggenhalli S. Nandagopal, 2023-05-26 This text provides a clear and concise understanding of the principles and applications of chemical engineering using a rigorous, yet easy-to-follow, presentation. The coverage is broad, and it includes all the relevant concepts such as mass and energy balances, mass transfer, chemical reaction engineering, and many more. Elucidation of the principles is further reinforced by examples and practice problems with detailed solutions. Firmly grounded in the fundamentals, the book maximizes readers’ capacity to take on new problems and challenges in the field with confidence and conviction. Providing a ready reference and review of essential principles and their applications in chemical engineering, the book is ideal for undergraduate chemical engineering students, as well as practicing engineers preparing for the engineering license exams (FE and PE) in USA and abroad.
  phase diagram for carbon dioxide: Advances in Carbon Dioxide Compression and Pipeline Transportation Processes Andrzej Witkowski, Andrzej Rusin, Mirosław Majkut, Sebastian Rulik, Katarzyna Stolecka, 2015-05-25 Providing a comprehensive analysis of CO2 compression, transportation processes and safety issues for post combustion CO2 capture applications for a 900 MW pulverized hard coal-fired power plant, this book assesses techniques for boosting the pressure of CO2 to pipeline pressure values with a minimal amount of energy. Four different types of compressors are examined in detail: a conventional multistage centrifugal compressor, integrally geared centrifugal compressor, supersonic shock wave compressor, and pump machines. The study demonstrates that the total compression power is closely related to the thermodynamic process and is not determined by compressor efficiency alone. Another problem addressed is that of CO2 pipeline transport from the compressor outlet site to a disposal site under heat transfer conditions. The book also features an analysis of simulations and models that are used to determine the maximum safe pipeline distance to subsequent booster stations as a function of inlet pressure, ambient temperature, thickness of the thermal insulation and ground-level heat flux conditions. This book focuses on compression as well as transportation processes with particular emphasis on the safety risks related to the transport of CO2. The most important problem in terms of environmental protection is ensuring precise and reliable hazard identification. As hazards can only be managed effectively if they are properly identified, problems involving the discharge and atmospheric dispersion of CO2 are also discussed.
  phase diagram for carbon dioxide: Advanced Chemistry Michael Clugston, Rosalind Flemming, 2000-06-08 Carefully researched by the authors to bring the subject of chemistry up-to-date, this text provides complete coverage of the new A- and AS-level core specifications. The inclusion of objectives and questions make it suitable for self study.
  phase diagram for carbon dioxide: Physical Chemistry Robert J. Silbey, Robert A. Alberty, Moungi G. Bawendi, George A. Papadantonakis, 2022-06-15 Ever since Physical Chemistry was first published in 1913, it has remained a highly effective and relevant learning tool thanks to the efforts of physical chemists from all over the world. Each new edition has benefited from their suggestions and expert advice. The result of this remarkable tradition is now in your hands.
  phase diagram for carbon dioxide: Carbon Dioxide Utilisation Peter Styring, Elsje Alessandra Quadrelli, Katy Armstrong, 2014-09-13 Carbon Dioxide Utilisation: Closing the Carbon Cycle explores areas of application such as conversion to fuels, mineralization, conversion to polymers, and artificial photosynthesis as well as assesses the potential industrial suitability of the various processes. After an introduction to the thermodynamics, basic reactions, and physical chemistry of carbon dioxide, the book proceeds to examine current commercial and industrial processes, and the potential for carbon dioxide as a green and sustainable resource. While carbon dioxide is generally portrayed as a bad gas, a waste product, and a major contributor to global warming, a new branch of science is developing to convert this bad gas into useful products. This book explores the science behind converting CO2 into fuels for our cars and planes, and for use in plastics and foams for our homes and cars, pharmaceuticals, building materials, and many more useful products. Carbon dioxide utilization is a rapidly expanding area of research that holds a potential key to sustainable, petrochemical-free chemical production and energy integration. - Accessible and balanced between chemistry, engineering, and industrial applications - Informed by blue-sky thinking and realistic possibilities for future technology and applications - Encompasses supply chain sustainability and economics, processes, and energy integration
  phase diagram for carbon dioxide: Phase Rule and Its Applications Suruchi, Sheza Zaidi, 2022-06-01 The book covers the fundamental concepts of phases, phase diagrams and their applications. Stress is on understanding and not on memorization. The book has descriptive passages and diagrams (cooling curves) that help students gain a solid foundation in subject. This text will help them learn phase rule faster. It also contains numerous phase diagrams. Note: T& F does not sell or distribute the Hardback in India, Pakistan, Nepal, Bhutan, Bangladesh and Sri Lanka.
  phase diagram for carbon dioxide: Green Chemistry Experiments: A Monograph R.K. Sharma, Indu Tucker Sidhwani, M. K. Chaudhuri, 2012-12-13 Green Chemistry Network Centre (GCNC) has been established in Delhi University under the recommendation of a panel of world leaders headed by Professor Paul Anastas (known as Father of Green Chemistry) with the following aims: Build up a network for exchange of expertise, discussion and knowledge between industrialists and academicians as well as between chemists and engineers with interests and expertise relevant to Green Chemistry. Prepare and disseminate the educational materials on Green Chemistry for school, college and university levels through specially designed courses (e.g. add-on courses) with special focus on laboratory experiments. Design training not just to expose the chemists to the concepts, principles and methodologies of Green Chemistry but also to empower them to bring this new knowledge back to their institution or industries. Translate existing Green Chemistry materials for broader distribution through the network all over India. GCNC received the prestigious ChemRAWN XIV-GCI Developing and Emerging Nations Grant Award, consecutively for the year 2005, 2006 & 2007 from American Chemical Society's Green Chemistry Institute for these activities.